A couple of notes for new Neteller users. You can deposit directly from your bank to a pokersite using Neteller's Instacash feature, but there is a fee for this service. A few of the poker sites do waive the fees, but be forewarned.
The same is true for various methods of accessing your money. You can get a Neteller debit card and access your money right away, but there are fees. If you are willing to wait a few days, transfers back to your bank are free.
Although it usually takes 2 business days to get your money, I have heard a recent report of it taking longer, probably due to higher volumes during the pre-holiday season. So don't get in a panic if you don't see your money the next day.
I've been using Neteller for over a year and I think it is the best way to go.